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Isolation and characterization of ceramide N-acylaminoethylphosphonate and its partial synthesis"}]}, "item_2_biblio_info_8": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1971", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "21", "bibliographicPageEnd": "30", "bibliographicPageStart": "24", "bibliographic_titles": [{"bibliographic_title": "滋賀大学教育学部紀要, 自然科学"}]}]}, "item_2_description_43": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"subitem_description": "Departmental Bulletin Paper", "subitem_description_type": "Other"}]}, "item_2_description_5": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": " The naturally occurring N-acyl derivatives of glycerophospholipid(e. g. N-acylphosphatidylethanolamine from plant seeds and N-acylphosphatidylserine from sheep blood)\nhas been established by a few workers, but so far as we know in the case of the\nderivatives of sphingolipid, no such substance has previously been reported. The present authors prepared a large amount of sphingolipid fractions from the fresh-water bivalve, Corbicula sandai, and separated them by Florisil column chromatography, followed by preparative thin layer chromatography. We succeeded in obtaining a notable phospholipid which was negative with ninhydrin reagent, and gave a faster-moving spot on thin layer chromatography. The lipid was practically\nfree from sugar and glycerol, and on hydrolysis liberated only aminoethylphosphonic\nacid as phosphorus component. And quantitative analyses of P, N, fatty acid and sphingosine base showed to be in a ratio of 1:2:2:1. From these results the lipid was proved to be ceramide N-(acyl)aminoethylphosphonate (N-acyl CAEP). The component fatty acids of N-acyl CAEP consisted mainly of palmitic and stearic acids, but no unsaturated ones could be detected.\nOn the other hand the partial synthesis of N-palmitoyl CAEP was studied by using CAEP from the bivalve as a starting material and comparative examinations were made concerning chemical nature of the synthetic N-acyl derivatives with that of the isolated one. Similar results were obtained from infrared spectra, mobilities on thin layer chromatography and resistance against phospholipase C.", "subitem_description_type": "Abstract"}]}, "item_2_description_7": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "滋賀大学教育学部紀要, 自然科学, 第21号, pp.24-30", "subitem_description_type": "Other"}]}, "item_2_full_name_2": {"attribute_name": "著者(ヨミ)", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "6143", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "イワモリ, マサオ"}]}, {"nameIdentifiers": [{"nameIdentifier": "6144", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "スギタ, ムツミ"}]}, {"nameIdentifiers": [{"nameIdentifier": "6145", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "ホリ, タロウ"}]}]}, "item_2_full_name_3": {"attribute_name": "著者別名", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "6146", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "Iwamori, Masao"}]}, {"nameIdentifiers": [{"nameIdentifier": "6147", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "Sugita, Mutsumi"}]}, {"nameIdentifiers": [{"nameIdentifier": "6148", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "Hori, Taro"}]}]}, "item_2_publisher_35": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "滋賀大学教育学部"}]}, "item_2_source_id_11": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AN00101060", "subitem_source_identifier_type": "NCID"}]}, "item_2_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0488-6291", "subitem_source_identifier_type": "ISSN"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "metadata only access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_14cb"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "岩森, 正男"}], "nameIdentifiers": [{"nameIdentifier": "6140", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "杉田, 陸海"}], "nameIdentifiers": [{"nameIdentifier": "6141", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "堀, 太郎"}], "nameIdentifiers": [{"nameIdentifier": "6142", "nameIdentifierScheme": "WEKO"}]}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "貝類脂質の生化学的研究 : Ⅹ. セラミド・アミノエチルホスホネートのN-アシル誘導体の単離と半合成", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "貝類脂質の生化学的研究 : Ⅹ. セラミド・アミノエチルホスホネートのN-アシル誘導体の単離と半合成"}]}, "item_type_id": "2", "owner": "1", "path": ["137"], "permalink_uri": "http://hdl.handle.net/10441/4569", "pubdate": {"attribute_name": "公開日", "attribute_value": "2009-06-17"}, "publish_date": "2009-06-17", "publish_status": "0", "recid": "1459", "relation": {}, "relation_version_is_last": true, "title": ["貝類脂質の生化学的研究 : Ⅹ. セラミド・アミノエチルホスホネートのN-アシル誘導体の単離と半合成"], "weko_shared_id": -1}
貝類脂質の生化学的研究 : Ⅹ. セラミド・アミノエチルホスホネートのN-アシル誘導体の単離と半合成
http://hdl.handle.net/10441/4569
http://hdl.handle.net/10441/456987491637-0774-4946-b20a-3002f0adae3b
Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2009-06-17 | |||||
タイトル | ||||||
タイトル | 貝類脂質の生化学的研究 : Ⅹ. セラミド・アミノエチルホスホネートのN-アシル誘導体の単離と半合成 | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
アクセス権 | ||||||
アクセス権 | metadata only access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
著者 |
岩森, 正男
× 岩森, 正男× 杉田, 陸海× 堀, 太郎 |
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著者(ヨミ) | ||||||
姓名 | イワモリ, マサオ | |||||
著者(ヨミ) | ||||||
姓名 | スギタ, ムツミ | |||||
著者(ヨミ) | ||||||
姓名 | ホリ, タロウ | |||||
著者別名 | ||||||
姓名 | Iwamori, Masao | |||||
著者別名 | ||||||
姓名 | Sugita, Mutsumi | |||||
著者別名 | ||||||
姓名 | Hori, Taro | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The naturally occurring N-acyl derivatives of glycerophospholipid(e. g. N-acylphosphatidylethanolamine from plant seeds and N-acylphosphatidylserine from sheep blood) has been established by a few workers, but so far as we know in the case of the derivatives of sphingolipid, no such substance has previously been reported. The present authors prepared a large amount of sphingolipid fractions from the fresh-water bivalve, Corbicula sandai, and separated them by Florisil column chromatography, followed by preparative thin layer chromatography. We succeeded in obtaining a notable phospholipid which was negative with ninhydrin reagent, and gave a faster-moving spot on thin layer chromatography. The lipid was practically free from sugar and glycerol, and on hydrolysis liberated only aminoethylphosphonic acid as phosphorus component. And quantitative analyses of P, N, fatty acid and sphingosine base showed to be in a ratio of 1:2:2:1. From these results the lipid was proved to be ceramide N-(acyl)aminoethylphosphonate (N-acyl CAEP). The component fatty acids of N-acyl CAEP consisted mainly of palmitic and stearic acids, but no unsaturated ones could be detected. On the other hand the partial synthesis of N-palmitoyl CAEP was studied by using CAEP from the bivalve as a starting material and comparative examinations were made concerning chemical nature of the synthetic N-acyl derivatives with that of the isolated one. Similar results were obtained from infrared spectra, mobilities on thin layer chromatography and resistance against phospholipase C. |
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引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 滋賀大学教育学部紀要, 自然科学, 第21号, pp.24-30 | |||||
書誌情報 |
滋賀大学教育学部紀要, 自然科学 号 21, p. 24-30, 発行日 1971 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0488-6291 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00101060 | |||||
タイトル(ヨミ) | ||||||
その他のタイトル | カイルイ シシツ ノ セイカガクテキ ケンキュウ 10 セラミド アミノエチルホスホネート ノ N アシル ユウドウタイ ノ タンリ ト ハンゴウセイ | |||||
その他の言語のタイトル | ||||||
その他のタイトル | Biochemistry of Shellfish Lipids Ⅹ. Isolation and characterization of ceramide N-acylaminoethylphosphonate and its partial synthesis | |||||
出版者 | ||||||
出版者 | 滋賀大学教育学部 | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | Departmental Bulletin Paper |